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5) Conformation of Furanose Ring The Sugar forming a 5-membered ring, such as Deoxyribose, Ribose etc called Furanose Ring, takes special conformations, since the pentagon shaped ring has an inside angle of 108 , where carbons forming the pentagon have bonding angles 109 28' causing C2' to raise upwards from the plane of 5-ring in some cases and C3' to raise in other cases. This plays an important role when assembling DNA, tRNA models.C3'-endo: Twist Deoxyribose (or Ribose) with both hands so that C3' toward Viewer is raised while C2' is lowered when three atom-balls C4' -O1' -C1' are horizontally viewed on a line. ![]() Fig. 16
C2'-endo : Twist Deoxyribose (or Ribose) to reverse direction, i,e., C3' lower and C2' raised. ![]() Fig. 17
You may regard all the furanose ring confomations simply either as C3' -end or as C2' -end to simplify your assembling work. When the model is almost completed, make corrections, if any, faithfully according to the above. | ||||||||||||||||||
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HGS Molecular Structure Model HGS HINOMOTO PLASTICS CO., LTD. 1-10-24, Meguro-Honcho, Meguro-ku, Tokyo, Japan PHONE: +81-3-3714-7226 FAX: +81-3-3714-4657 E-MAIL(technical support): hgs@po.sphere.ne.jp E-MAIL(order support): t_kaneko@maruzen.co.jp |